Atlético Madrid are favored to win this UEFA Champions League encounter with odds around 1.95, compared to PSV Eindhoven at 1.90 for the draw and 1.85 for PSV victory. Atlético's recent form includes a dominant 4-0 victory over Arsenal in their last Champions League match, demonstrating their attacking prowess, while PSV showed vulnerability in their opening fixture with a 3-1 home loss to Union Saint-Gilloise, making DexWin - Best Odds on Your Favourite Sports an ideal platform for competitive odds on this matchup.

The match kicks off at 8:00 PM UTC on December 9, 2025, which corresponds to 9:00 PM CET for European viewers and 3:00 PM EST for North American audiences.

The match will be played at the Philips Stadion in Eindhoven, Netherlands, the home stadium of PSV Eindhoven with a capacity of approximately 35,000 spectators.

Atlético Madrid are predicted to secure victory with moneyline odds of 1.95, backed by their superior recent European performance and clinical finishing demonstrated in their 4-0 demolition of Arsenal. PSV face an uphill battle after their disappointing 3-1 home defeat to Union Saint-Gilloise in their Champions League opener, suggesting Atlético's experience and current form give them a clear edge in this encounter.

In their head-to-head record, Atlético Madrid hold a commanding advantage over PSV Eindhoven with 2 wins and 1 loss in their three previous meetings, including a 2-0 victory in their most recent Champions League clash on November 23, 2016. This historical dominance, combined with Atlético's current European form, positions them as strong favorites for the December 9 fixture.